A catalogue of Chinese species of the genus Euscorpiops Vachon, 1980 is provided. There are 10 species in total, none of them was recorded from China in “Catalog of the Scorpions of the World” (Fet et al., 2000). A new species, E. puerensis sp. nov. from southern Yunnan is described and illustrated. E. puerensis sp. nov. is characterized by having 18 external trichobothria (5 eb, 2 esb, 2 em, 4 est, 5 et), and 10 or 11 ventral trichobothria in the pedipalp patella; chela with a length/ width ratio average of 2.7 on males and females; pedipalp chela fingers on adult females and males scalloped; pectinal teeth count 7–8; pectinal fulcra present.