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Angewandte Chemie International Edition
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Isolation and Characterization of the Homoleptic Nickel(I) and Nickel(II) Bis‐benzene Sandwich Cations

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 16 Nov 2022 Germany Publisher:WileyJournal:Angewandte Chemie International Edition, volume 61 (issn: 1433-7851, eissn: 1521-3773, Copyright policy )Funded by:DFG | unidentified
Authors: Manuel Schmitt; Maximilian Mayländer; Tim Heizmann; Sabine Richert; Christine Bülow; Konstantin Hirsch; Vicente Zamudio‐Bayer; +2 Authors

doi: 10.1002/anie.202211555

pmid: 36197000

pmc: PMC10099793

Isolation and Characterization of the Homoleptic Nickel(I) and Nickel(II) Bis‐benzene Sandwich Cations

Abstract

AbstractA stable salt of the metalloradical [Ni(C6H6)2]+ hitherto unknown in the condensed phase was synthesized from [Ni(CO)4]+[WCA]− and benzene ([WCA]−=[F{Al(ORF)3}2]−; RF=C(CF3)3). Single crystal XRD reveals a remarkable asymmetrically η3,η6‐slipped sandwich structure. The magnetic properties of the [Ni(C6H6)2]+ cation were determined in solution and in the gas phase. Oxidation with the synergistic Ag+/0.5 l2 system led to the salt [Ni(C6H6)2]2+([WCA]−)2. All products were fully characterized by means of IR, Raman, NMR/EPR, single crystal and powder XRD.

Country
Germany
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Keywords

Communications, Matter Dynamics Mechanisms and Control

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    influence
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Top 10%
Average
Top 10%
Green
hybrid