Complications from Dual Roles of Sodium Hydride as a Base and as a Reducing Agent
Copyright policy ) Dusan, Hesek; Mijoon, Lee; Bruce C, Noll; Jed F, Fisher; Shahriar, Mobashery;
Complications from Dual Roles of Sodium Hydride as a Base and as a Reducing Agent
Sodium hydride is a common reagent for substrate activation in nucleophilic substitution reactions. Sodium hydride can behave both as a base and as a source of hydride. This dual ability in the presence of an electrophile such as benzyl bromide results in the formation of byproducts when dimethylformamide or acetonitrile are used as solvents for these reactions. The structural nature of these byproducts is revealed in this report.
- University of Notre Dame United States
Acetonitriles, Reducing Agents, Solvents, Dimethylformamide, Sodium Compounds
Acetonitriles, Reducing Agents, Solvents, Dimethylformamide, Sodium Compounds
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).34 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 10% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 10% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 10%
citations
Citations provided by BIP!
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
Citations provided by BIP!popularityPopularity provided by BIP!
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
Popularity provided by BIP! 34
Top 10%
Top 10%
Top 10%
bronze
Fields of Science