Studies on the constituents of aceraceae plants. III. Structure of acerogenin B from Acer nikoense Maxim.

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1980 English Publisher:Pharmaceutical Society of JapanJournal:Chemical and Pharmaceutical Bulletin, volume 28, pages 1,300-1,303 (issn: 0009-2363, eissn: 1347-5223,

Authors: MASAYOSHI KUBO; TAKAO INOUE; MASAHIRO NAGAI;

doi: 10.1248/cpb.28.1300

Studies on the constituents of aceraceae plants. III. Structure of acerogenin B from Acer nikoense Maxim.

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Abstract

Acerogenin B (3), C19H22O3, mp 179°, [α]23D±0°, a new diarylheptanoid of diphenyl ether type, was isolated from an acid hydrolysate of the glycoside mixture extracted from the bark of Acer nikoense MAXIM. The structure of acerogenin B (3) was established as formula 3 in Chart 1 on the basis of the spectral data and chemical correlation with acero-genin A (2). Acerogenin B (3) was considered to be a racemic compound in view of the optical inactivity of 3 and its derivatives (4 and 10).

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Studies on the constituents of aceraceae plants. IV. Carbon-13 nuclear magnetic resonance spectra of acerogenin A, rhododendrol and related compounds, and structure of aceroside IV from Acer nikoense.
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