Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions
Authors: Daxiang Gui; Tao Zheng; Jian Xie; Yawen Cai; Yaxing Wang; Lanhua Chen; Juan Diwu; +2 Authors
Daxiang Gui; Tao Zheng; Jian Xie; Yawen Cai; Yaxing Wang; Lanhua Chen; Juan Diwu; Zhifang Chai; Shuao Wang;
pmid: 27989170
Significantly Dense Two-Dimensional Hydrogen-Bond Network in a Layered Zirconium Phosphate Leading to High Proton Conductivities in Both Water-Assisted Low-Temperature and Anhydrous Intermediate-Temperature Regions
Abstract
A highly stable layered zirconium phosphate, (NH4)2[ZrF2(HPO4)2] (ZrP-1), was synthesized by an ionothermal method and contains an extremely dense two-dimensional hydrogen-bond network that is thermally stable up to 573 K, leading to combined ultrahigh water-assisted proton conductivities of 1.45 × 10-2 S cm-1 at 363 K/95% relative humidity and sustainable anhydrous proton conductivity of 1.1 × 10-5 S cm-1 at 503 K.
Related Organizations
- Soochow University China (People's Republic of)
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
popularity
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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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