Carboxylic acids as an oxolation source for the synthesis of titanium oxo organo clusters

descriptionPublicationkeyboard_double_arrow_right Article 01 May 2001 English Publisher:Informa UK LimitedJournal:High Pressure Research, volume 20, pages 63-70 (issn: 0895-7959, eissn: 1477-2299,

Authors: N. Steunou; R. Portal; C. Sanchez;

doi: 10.1080/08957950108206153

Carboxylic acids as an oxolation source for the synthesis of titanium oxo organo clusters

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Abstract

Abstract Three titanium oxo-isopropoxo clusters [Ti6O4(OAc)4(OPr1)12] (1) and [Ti12O16(OPr1)16] (2) and [Ti17O24(OPri)20](3) are (3) are obtained by a solvothermal approach which does not involve the direct hydrolysis of titanium alkoxide precursor. Water is generated in-situ through esterification reactions induced by acetic acid. The molecular structures of these complexes have been resolved by single crystal X-ray diffraction. The nuclearity of these clusters increases with acetic acid/Ti ratio and temperature.

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Centre national de la recherche scientifique
France

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