Pioneer Venus Orbiter measurements of planetary contrast at the Venus cloud tops are discussed. Images of the cloud tops at wavelengths between 1990 and 3400 A were obtained by the Pioneer UV Spectrometer together with broadband imagery and polarimetry at 2700 and 3650 A from the Orbiter Cloud Photopolarimeter at Venus phase angles of 33 to 130 deg. The planet is found to be darkest at the point where the UV Spectrometer line of sight penetrates perpendicular to the cloud tops, indicating that the absorbing material must be deep in the atmosphere. The contrast observed at wavelengths shortward of 3200 A is explained by SO2 absorption in the dark regions, while the persistence of the contrast at longer wavelengths requires the presence of an additional absorber or absorbers closely associated with the SO2, and a haze of submicron particles overlying the cloud tops in the bright regions. The correlations found between contrast and polarization indicate that no single constituent or change in vertical structure can account for the UV contrast. The origin of the markings is instead explained by a model in which absorbers subject to photochemical destruction are mixed upward into the cloud top region.