Catalyzing the transition to non-transition metal-mediated C-H amination
Universiteit van Amsterdam, Faculteit der Natuurwetenschappen, Wiskunde en Informatica (Faculty of Science), Van t Hoff Institute for Molecular Sciences (HIMS), Homogeneous, Supramolecular and Bio-Inspired Catalysis , Universiteit van Amsterdam , Universiteit van Amsterdam, Faculteit der Natuurwetenschappen, Wiskunde en Informatica (Faculty of Science), Van t Hoff Institute for Molecular Sciences (HIMS)
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Universiteit van Amsterdam, Faculteit der Natuurwetenschappen, Wiskunde en Informatica (Faculty of Science), Van t Hoff Institute for Molecular Sciences (HIMS), Homogeneous, Supramolecular and Bio-Inspired Catalysis , Universiteit van Amsterdam , Universiteit van Amsterdam, Faculteit der Natuurwetenschappen, Wiskunde en Informatica (Faculty of Science), Van t Hoff Institute for Molecular Sciences (HIMS)
Expensive transition metals are currently the dominant force in the design of new catalysts. This project aims to challenge this principle by focussing on iron, aluminium and zinc based complexes that, when combined with specific redox-active ligands, should be amenable to facilitate radical-type reactions. This concept will be tested in C-H amination reactions that can give access to valuable amine products.
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