The vision of the proposed research is to develop activated carbon adsorbents and system models to improve the efficiency, flexibility and operability of IGCC processes . Novel activated carbon (AC) adsorbents prepared from resin precursors have the ability to be tailored to control both their CO2 adsorption capacity and isotherm shape. As a result, they offer significant advantages over solvent-based systems for the pre-combustion capture of CO2 in integrated combined cycle gasification (IGCC) processes in terms of cost and flexibility. The research will focus on gaining a fundamental understanding of how the porosity and surface functionality of resin-derived carbons, both in bead and monolith forms, controls their CO2 adsorption under actual process conditions in the presence of moisture and other gases. It is likely to achieve high CO2 removals in IGCC, more than one bed will be needed operating at different pressures. As a result adsorbents displaying high uptakes at low partial pressures (<5 bar) of CO2 will also be investigated. Indeed adsorbents displaying high uptakes at low partial pressures will also find applications in post-combustion capture and selectively removing CO2 from blast furnace gas during iron making. In parallel, the project will also consider how the unique performance of the AC sorbents for CO2 capture will improve the operability of IGCC power plants. Comparisons of emissions, resource requirements and costs with varying levels on CO2 removal via adsorption will be made on a systematic basis allowing different design options and control strategies to be devised, in order to minimise the effects of CO2 capture upon the overall process efficiency. In the research programme, the results from the first theme on the efficacy of the various ACs will be used as the design basis in the second theme on modelling the performance of IGCC plants. The proposal brings the balanced expertise together from five academic institutes to increase our understanding of AC adsorbents for pre-combustion capture and how they will improve the operability and flexibility of IGCC plants. The internationally recognized capability for CO2 adsorbents and power plant control at Nottingham and Birmingham and the complementary stengths of the Institute Coal Chemistry (ICC) and Tsinghau Univeristy make it logical for the partners to combine their strengths to address more effective capture of CO2 in IGCC and the implications of this on overall plant operation. Regarding the Chinese partners, Tsinghua have studied the IGCC process for over 10 years and they have developed the first complete simplified IGCC dynamical mathematical model and simulation program). ICC CAS have been involved in may aspects of gasification and are already working with the UoN on active carbons for post-combustion capture (ICUK award). In relation to the Call, this proposal addresses both:(i) New technologies based on material advances(ii) Modelling and simulation and of capture plants employing the advanced materials

Many high-value manufactured components that are made in the UK are used in safety critical structures such as nuclear plants and aircraft engines. Such components must be checked periodically for the presence of flaws and other precursors to the component failing. This is performed at various stages in the lifetime of the component: at the manufacturing stage, periodically while the component is in service, and to assess the component for remanufacturing at the end of its lifetime. Components must be checked non-destructively, which is challenging; normally the component's design is not optimised to maximise the probability of detecting a flaw using non-destructive evaluation (NDE). The Engineering Design Challenge is to bring NDE considerations into the design engineer's virtual design toolbox. This project aims to enable design engineers to optimise the design of a given component such that they maximise their ability thereafter to test this component non-destructively for the presence of any flaws. Thus flaw-detectability will used as an additional design criterion. This will also help in remanufacturing as we will be more able to assess the integrity of used components. In this way we will improve society by having safer aircraft, nuclear plants and oil pipelines, improve the environment by having fewer wasted components and using less energy, and improve the UK economy by developing the UK's expertise in these high value sectors. The most common modality in non-destructive evaluation of these safety critical structures is ultrasound transducer imaging. The Centre for Ultrasonic Engineering (CUE) at the University of Strathclyde has extensive experience in the computer simulation and mathematical modelling of ultrasonic transducers and in their use in NDE. They are ideally placed to develop such a software platform. The University of Strathclyde also hosts the Scottish Institute for Remanufacture (SIR), so the project will utilise the research expertise in this area in conjunction with that of CUE. This project will enable CUE and SIR to form a new alliance with experimental design and tomographic imaging experts from the School of Geosciences at the University of Edinburgh. In the Geosciences, sophisticated imaging methods are used to image the Earth's subsurface, and design theory is developed to optimise imaging array geometries and methods. This combined capability will enable the joint project team to develop a virtual environment where techniques for designing and imaging the internal structures of safety critical components can be assessed and optimised.

Many high-value manufactured components that are made in the UK are used in safety critical structures such as nuclear plants and aircraft engines. Such components must be checked periodically for the presence of flaws and other precursors to the component failing. This is performed at various stages in the lifetime of the component: at the manufacturing stage, periodically while the component is in service, and to assess the component for remanufacturing at the end of its lifetime. Components must be checked non-destructively, which is challenging; normally the component's design is not optimised to maximise the probability of detecting a flaw using non-destructive evaluation (NDE). The Engineering Design Challenge is to bring NDE considerations into the design engineer's virtual design toolbox. This project aims to enable design engineers to optimise the design of a given component such that they maximise their ability thereafter to test this component non-destructively for the presence of any flaws. Thus flaw-detectability will used as an additional design criterion. This will also help in remanufacturing as we will be more able to assess the integrity of used components. In this way we will improve society by having safer aircraft, nuclear plants and oil pipelines, improve the environment by having fewer wasted components and using less energy, and improve the UK economy by developing the UK's expertise in these high value sectors. The most common modality in non-destructive evaluation of these safety critical structures is ultrasound transducer imaging. The Centre for Ultrasonic Engineering (CUE) at the University of Strathclyde has extensive experience in the computer simulation and mathematical modelling of ultrasonic transducers and in their use in NDE. They are ideally placed to develop such a software platform. The University of Strathclyde also hosts the Scottish Institute for Remanufacture (SIR), so the project will utilise the research expertise in this area in conjunction with that of CUE. This project will enable CUE and SIR to form a new alliance with experimental design and tomographic imaging experts from the School of Geosciences at the University of Edinburgh. In the Geosciences, sophisticated imaging methods are used to image the Earth's subsurface, and design theory is developed to optimise imaging array geometries and methods. This combined capability will enable the joint project team to develop a virtual environment where techniques for designing and imaging the internal structures of safety critical components can be assessed and optimised.

To achieve the UK's ambitious target of reducing greenhouse gas emissions by 80% by 2050, it is widely accepted that from ca. 2030 Carbon Capture and Storage (CCS) needs to be fitted to both coal and natural gas fired power plants. The flue gas characteristics of natural fired gas power plants, mostly operating in a combined cycle of gas turbine and steam turbine (NGCC), differ significantly from those from coal-fired power plants. Comparing to the flue gas of the same size coal-fired power plant, the flue gas of a NGCC power plant contains significantly lower CO2 (3-5 vs. 13-15%) and higher O2 concentrations (12-15 vs. 2-4%) and has ca. 50% higher flow rate, which make the separation of CO2 equally, if not more, challenging. The most mature PCC technology, CO2 amine scrubbing, suffers from well-know problems of high energy penalty, oxidative solvent degradation and corrosion, large capture plant footprint and high rate of water consumption. A new generation of PCC technologies for NGCC power plants which overcome these drawbacks need to developed and demonstrated in the next 10 ~ 20 years in order for their commercialisation from ca. 2030. Solid adsorbents looping technology (SALT) is widely recognised as having the potential to be a viable next generation PCC technology for CO2 capture compared to the state-of-art amine scrubbing, offering potentially significantly improved process efficiency at much reduced energy penalty, lower capital and operational costs and smaller plant footprints. The aim of this project is to overcome the performance barriers for implementing the two types of candidate adsorbent systems developed at Nottingham, namely the supported/immobilised polyamines and potassium-promoted co-precipitated sorbent system, in the solid looping technology specifically for NGCC power plants, which effectively integrates both materials and process development and related fundamental issues underpinning the technology development. The objectives are: 1. To overcome the following major specific challenges: (a) To examine and enhance the oxidative and/or hydrolytic stability of supported/immobilised polyamine adsorbents and hence to identify efficient and cost-effective management strategies for spent materials. (b) To optimise the formulation and preparation of the potassium-promoted co-precipitated sorbents for improved working capacity, reaction kinetics and regeneration behaviour at lower temperatures. (c.) To gain comprehensive understanding of to what degree and how different flue gas conditions, particularly oxygen and moisture, can impact the overall performance of adsorbent materials and related techno-economic performance of a solid looping process. 2. To produce kilogram quantities of the optimum adsorbent materials and then demonstrate their performances over repeated adsorption/desorption cycles and to establish the optimal process thermodynamics in fluidized bed testing. 3. To investigate a novel rejuvenation strategy for oxidised polyethyleneimines involving low temperature hydrogenation. 4. To conduct techno-economic studies to assess the cost advantages of the solids looping technology for NGCC power plants over amine scrubbing based on the improved adsorbent performance and optimised process configuration achieved in the project. The know-how acquired in this project will be of direct benefit to academics, CCS research community, power generation and energy industries, energy policy makers/regulators, environmental organisations and government departments such as DECC. The successful delivery of the proposed project represents a major step forward in the development and demonstration of the novel and cost-effective Solids Adsorbents Looping CO2 capture technology for NGCC power stations.

The Gas-FACTS programme will provide important underpinning research for UK CCS development and deployment on natural gas power plants, particularly for gas turbine modifications and advanced post combustion capture technologies that are the principal candidates for deployment in a possible tens-of-£billions expansion of the CCS sector between 2020 and 2030, and then operation until 2050 or beyond, in order to meet UK CO2 (carbon dioxide) emission targets. Gas CCS R&D is an emerging field and many of the concepts and underlying scientific principles are still being 'invented'. But on-going UK infrastructure investments and energy policy decisions are being made which would benefit from better information on relevant gas CCS technologies, making independent, fundamental studies by academic researchers a high priority. In addition, the results of this project will provide an essential basis for further work to extract the maximum research benefits from the UK CCS demonstration programme and help to develop more advanced gas CCS technologies for a second tranche of CCS deployment. The programme will also develop rigorous assessment methods and a framework to maximise pathways to impact that could support other RCUK research activities on gas CCS. Globally, there is already interest in gas CCS in Norway, California and the Middle East, and this is likely to become more widespread if cheaper gas leads to more widespread use. This work will be undertaken through work packages with the following aims: WP1: To quantify the scope of gas turbine modifications to improve the technical, environmental and economic performance of integrated CO2 capture on CCGT plants. Small gas turbines will be modified to run with steam or recycled flue gas replacing some of the normal air feed to increase back-end CO2 concentrations (which will help make the CO2 easier to capture). WP2: To quantify through modelling and experimental testing the scope for improving post-combustion capture system performance on CCGT plants through a combination of advanced liquid solvents, including novel amine mixtures, and improved transient performance. Solvents that are used to take up CO2 and then release it in a pure form that can be stored underground will be modified so that the amount of energy required to do this is reduced. The equipment the solvents are used in will also be designed to turn on and off quickly to allow CCS power plants to compensate for fluctuations in output from wind turbines. WP3: In close collaboration with an external Experts Group to undertake integration and whole systems performance assessments. This will include a 'Gas-FACTS Impact Handbook' combining impact tables with state-of-the-art surveys to ensure that pathways to impact pursued by Gas-FACTS researchers are co-ordinated with other significant activities, including excellent science and stakeholder plans, to maximise their effectiveness. Gas-FACTS results will be implemented in the freely-available IECM package for access by any potential users. WP4: Impact delivery and expert interaction activities will be based on establishing an Experts Group including representatives of the UK CCS academic community, global academic community, UK policymakers, UK Regulators, NGOs, power utilities, Original Equipment Manufacturers (OEMs), SMEs (Small and Medium Enterprises). WP4 will also run a programme of engagement activities to impact, including project meetings, specialist meetings on topical issues and results, web-based dissemination and document publication (reports, responses to Parliamentary inquiries, journal papers, articles etc.)