The importance, motivation and stimulus of this multi-disciplinary (chemical synthesis, liquid crystal and polymer science, optical technology and information storage) and international (UK, Japan, Denmark and USA) materials-related feasibility research proposal is to address the urgent global consumer requirement for an ever-increasing demand for higher data storage capacity. Current technologies such as conventional magneto-optical are fast becoming economically unviable and will soon reach their physical limitations of storage capacity. Hence new solutions are required to address this multi-billion dollar problem. Optical holographic storage is a critical next-generation technology that can support the growing information storage needs of the 21st century. Novel holographic read/write media are required. Our solution encompasses technology transfer between academia and industry via the synthesis, characterisation (chemical and optical) and industrial global evaluation of strategic organic materials as a source of novel highcapacity holographic read/write storage media. The materials are organic-based polyesters comprising both side-chain mesogenic and side-chain heterocyclic photoresponsive groups. The synthetic chemistry is versatile and readily amenable to large-scale production. The media will be industrially tested for 'end-user' commercial applications providing the project with focus, application and realism.

Among technically and economically viable renewable energy sources, wind power is that which exploitation has been growing fastest in the recent years. This research focuses on modern Horizontal Axis Wind Turbines (HAWT's), which typically feature two- or three-blade rotors. The span of HAWT blades can vary from a few meters to more than 100 meters, and their design is a complex multidisciplinary task which requires consideration of strong unsteady interactions of aerodynamic and structural forces. Some of the most dangerous sources of aerodynamic unsteadiness are a) yawed wind, due to temporary non-orthogonality of wind and rotor plane, and b) blade dynamic stall. These phenomena result in the blades experiencing time-varying aerodynamic forces, which can excite undesired structural vibrations. This occurrence, in turn, can dramatically reduce the fatigue life of the blades and their supporting structure, yielding premature mechanical failures. Events of this kind can compromise the technical and financial success of the installation, which heavily relies on fulfilling the expectations of minimal servicing on time-scales of the order of 10 to 30 years. These facts highlight the importance of the aeroelastic design process of HAWT blades. The unsteady aerodynamic loads required to determine the structural response must be understood and accurately quantified in the development phase of the turbine. Due to the sizes at stake, in most cases it is infeasible to perform aeroelastic testing, not only from an economic but also logistic viewpoint. Hence these aeroelastic issues can only be tackled by using accurate simulation tools.The general motivation of this project is two-fold: it aims both at enriching the knowledge of unsteady flows relevant to wind turbine aeroelasticity, and advancing the state-of-the-art of the computational technology to accomplish this task. These objectives are pursued by using a novel Computational Fluid Dynamics (CFD) approach to wind turbine unsteady aerodynamics. The unsteady periodic flow relevant to aeroelastic analyses is determined by solving the three-dimensional unsteady viscous flow equations with the nonlinear frequency-domain (NLFD) technology. The NLFD-CFD approach has been successfully applied to fixed-wing and turbomachinery aeroelasticity. This research will exploit this high-fidelity methodology to enhance the understanding of the severe unsteady aerodynamic forcing of HAWT blades, and substantially reduce computational costs with respect to conventional time-domain CFD analyses. This method is particularly well suited to investigate the unsteady aerodynamic blade loads associated with stall-induced vibrations and yawed wind. On the other hand, this technology will greatly help designers to develop new blades without relying on the database of existing airfoil data on which the majority of present analysis and design systems depend. One of the main results of this project will be to greatly reduce the dichotomy between the conflicting requirements of physical accuracy and computational affordability of the three-dimensional unsteady viscous flow models for wind turbine unsteady aerodynamics and aeroelasticity. The achievements of this research will benefit the British and European industry in that they will offer an effective tool to design more efficient and reliable blades. The NLFD-CFD technology will also provide deeper insight into unsteady aerodynamic phenomena which affect the fatigue life of wind turbines. In the next few years, the certification process of wind turbines will enforce stricter requirements on the industry. The developed technology will support the analyses required to meet enhanced certification standards. The Unsteady Aerodynamics Research Community as a whole will also benefit from this research, because its findings will enhance and consolidate the deployment of the NLFD technology in rotorcraft, turbomachinery, and aircraft aeroelasticity.

Solid oxide fuel cells are highly intricate devices with many interfaces which are typically formed at high temperatures. This places many constraints in terms of chemical and physical compatibility upon such devices limiting both performance and durability. Such problems strongly restrict materials choice and impose significant cost penalties on SOFC manufacture. The utilisation of solution methods to introduce part of the SOFCs active constituents is a highly attractive approach that has gained much interest in recent years. This can involve infiltration of nanoparticles or impregnation of precursor solutions to form phases in situ. Much lower reaction temperatures can be utilised avoiding problems with compatibility and affording wider materials choice. Typically such process involves formation of a scaffold structure by high temperature processing and then impregnation of an electrode by lower temperature methods. We have successfully applied this approach to three different novel variants of SOFC architectures. These are electrolyte supported oxide anodes, oxide anode supported and metal anode supported cells. Excellent performances can be obtained and good redox properties demonstrated; however, progress needs to be made to ensure high durability. The impregnates tend to form well dispersed nanoparticles, but these might be expected to agglomerate over time, in fuel cell operating conditions, to reduce overall performance. Through the national and European projects where we applied the impregnation concept, we have learned much about impregnation and how to develop appropriately dispersed electrode structures. The electrode structure is seen to evolve with use and clear opportunities exist to optimise structures through improved processing. Most important has been the realisation that there are strong interplays between the materials impregnated, the substrate and the solvent utilised. Even subtle changes in electrode composition, demand significant changes in impregnation chemistry to maintain the maximum levels of performance. In this project we seek to further develop control of this impregnation chemistry and hence to develop generic methods for developing controlled microstructures via solution routes across several platforms. These new chemistries will be applied to electrolyte- and anode-supported SOFC geometries and properties optimised for performance, durability and redox tolerance. The overall objective is to develop and demonstrate this new approach as one that can be successfully applied to manufacture of fuel cells that combine high performance with durability and resistance to contaminants. We will apply this approach typically for an impregnated oxide electrode with metallic catalyst to zirconia, strontium titanate and metal supports and develop our understanding of the fundamental chemistry across this range of platforms. By so doing we will develop methodologies to tailor impregnations over a broad range of composition space. Studies of performance, durability and resistance to contaminants utilising electrochemical, spectroscopic and microstructural techniques will be used to inform choice of impregnate systems. Final outcomes will be delivery of novel tailored chemistries for different SOFC application modes and geometries, demonstration of novel cell technologies with robust, high performance characteristics at SOFC developer ready scales and development of new routes and instrumentation for SOFC manufacture.