World-wide, energy conversion is currently dominated by the combustion of fossil fuels. Electricity generation and transport are key energy consumers and contribute significantly to atmospheric CO2, NOx, and particulate emission. There is an increasing awareness in the public eye of the potential impact of particulates on health. This includes a higher risk of cancer, asthma and a potential contribution to neurodegenerative disorders (e.g., Alzheimer's disease). In the UK, particulate matter (PM) from combustion processes is a significant contributor to poor air quality in urban areas; it has been reported that more than 25,000 deaths per year could be attributed to long-term exposure to anthropogenic particulate air pollution. As reported by DEFRA, poor air quality is the largest environmental risk to public health in the UK, contributing to an estimated £2.7 billion per year in lost productivity. Air pollution also results in damage to the natural environment, contributing to the acidification of soil and watercourses. An obvious solution might be to move towards the replacement of vehicles with electric, however, this technology is limited by range, recharge times and the cost of the battery - for which there is currently not the sufficient global infrastructure to directly replace vehicles powered by internal combustion engine powered. Another complementary solution is to find alternative fuels that are tailored to reduce destructive emissions such as NOx and particulates. This has the advantage that it could be rapidly deployed due to the overlap with existing fuel station infrastructure. The main aim of the proposed research is to provide a fundamental understanding of the combustion performance and emissions characteristics of key biofuels. This is vital knowledge to aid the development of next-generation low carbon technologies. The key objectives are: (1) to provide high-quality experimental data from a study of spray flame behaviour and emissions using advanced optical diagnostic techniques such as laser-induced breakdown spectroscopy and laser-induced fluorescence, (2) to develop new combustion chemical kinetic models, based on COSILAB (Combustion Simulation Laboratory software), predicting soot and NOx emissions and (3) to establish collaborations with industrial and academic partners to investigate power generation and transport applications for next-generation biofuels. In the proposed research, the targeted biofuels are: (1) ethanol, (2) iso-pentanol, (3) dimethyl ether (DME) and (4) combined fuels - ethanol, iso-pentanol, DME and biomethane. These key fuels are potentially next-generation biofuels. The production paths of these fuels are either well established or achievable. Ethanol and DME have already shown evidence of reduced emissions from engine tests. The understanding of combustion chemistry is essential to enable the delivery of a low NOx and soot emission combustion system. How the local chemistry is influenced by various turbulent flow conditions will be examined in detail.

World-wide, energy conversion is currently dominated by the combustion of fossil fuels. Electricity generation and transport are key energy consumers and contribute significantly to atmospheric CO2, NOx, and particulate emission. There is an increasing awareness in the public eye of the potential impact of particulates on health. This includes a higher risk of cancer, asthma and a potential contribution to neurodegenerative disorders (e.g., Alzheimer's disease). In the UK, particulate matter (PM) from combustion processes is a significant contributor to poor air quality in urban areas; it has been reported that more than 25,000 deaths per year could be attributed to long-term exposure to anthropogenic particulate air pollution. As reported by DEFRA, poor air quality is the largest environmental risk to public health in the UK, contributing to an estimated £2.7 billion per year in lost productivity. Air pollution also results in damage to the natural environment, contributing to the acidification of soil and watercourses. An obvious solution might be to move towards the replacement of vehicles with electric, however, this technology is limited by range, recharge times and the cost of the battery - for which there is currently not the sufficient global infrastructure to directly replace vehicles powered by internal combustion engine powered. Another complementary solution is to find alternative fuels that are tailored to reduce destructive emissions such as NOx and particulates. This has the advantage that it could be rapidly deployed due to the overlap with existing fuel station infrastructure. The main aim of the proposed research is to provide a fundamental understanding of the combustion performance and emissions characteristics of key biofuels. This is vital knowledge to aid the development of next-generation low carbon technologies. The key objectives are: (1) to provide high-quality experimental data from a study of spray flame behaviour and emissions using advanced optical diagnostic techniques such as laser-induced breakdown spectroscopy and laser-induced fluorescence, (2) to develop new combustion chemical kinetic models, based on COSILAB (Combustion Simulation Laboratory software), predicting soot and NOx emissions and (3) to establish collaborations with industrial and academic partners to investigate power generation and transport applications for next-generation biofuels. In the proposed research, the targeted biofuels are: (1) ethanol, (2) iso-pentanol, (3) dimethyl ether (DME) and (4) combined fuels - ethanol, iso-pentanol, DME and biomethane. These key fuels are potentially next-generation biofuels. The production paths of these fuels are either well established or achievable. Ethanol and DME have already shown evidence of reduced emissions from engine tests. The understanding of combustion chemistry is essential to enable the delivery of a low NOx and soot emission combustion system. How the local chemistry is influenced by various turbulent flow conditions will be examined in detail.

The UK needs carbon capture and storage (CCS) as part of its energy mix to minimise the cost of decarbonising our economy. CCS will have to fit into an electricity market that is increasingly dominated by inflexible nuclear and uncontrollable wind. It will therefore be vital that the CCS plants we develop are sufficiently flexible to interact with this new system, and balance the rapid start and cycling abilities with the lowest possible capital and operating costs. Flexible CCS will be characterised by the ability to simultaneously interact with the complex electricity system of the future and also the downstream CO2 transport and storage system. Rather than burning fuel purely in response to electricity price, CCS operators will also have to factor in waste storage costs, which will suffer similar complexity due to constraints on CO2 transport and injection rates and gas composition. This project will identify the flexibility bottlenecks in the CCS chain and also promising options for the development of resilient CCS systems. These models will internally calculate CCS plant load factors and electricity wholesale prices, thereby enabling a rigorous, technologically- and temporally-explicit, whole systems analysis. Feedback from CO2 storage operations will exert an as-yet unknown impact on the feasible operating space of the decarbonised power plant. We will explicitly quantify the interactions between the above- and below-ground links in the CCS chain. Sample CCS chains developed will be assessed in more detail concerning their broader role in the UK energy system. The implications of technological improvements in critical technologies such as advanced sorbents, improved air separation technologies and the availability of waste heat will also be considered. On a larger scale, the inter-operation of sample UK-specific CCS networks with intermittent renewable energy generation will be examined from an internally consistent whole-systems perspective. The internalisation of exogenous boundary conditions (e.g., the role of renewable energy and CCS plant load factors) and the development of multi-source-to-sink CCS system models will enable the most accurate assessment to date of how CCS will fit into the UK energy system and would interact with other energy vectors. The linking of CCS and renewable energy generation system models will allow us to examine the opportunities and impacts associated with the co-deployment of renewable energy and CCS in the UK. This will feed into a wider policy analysis that will examine the dynamics of changing system infrastructure at intermediate time periods between now and 2050. Dissemination of research output will be continuous over the duration of the project. We will engage with the academic community via publication in the international peer reviewed scientific literature and presenting at selected conferences. Owing to the topical nature of this research, public engagement is a priority for us. We plan on creating and managing a project webpage will provide real time insight into project progress and intermediate conclusions and results. All research papers and presentations will be available from this site. Similarly, we will conduct a continuous horizon scanning activity as part of this project. Our website will be continuously updated with a view to providing an understanding of where our research fits in the broader UK and international research arena. This work will be carried out via the development and integration of detailed mathematical models of each link in the CCS chain. We have engaged with a leading UK-based software development company with whom we will work to make these models available to the academic and broader stakeholder community. Further, a version of the modelling tools suitable for use by the general public will also be prepared. It is expected that this tool will be analogous in form and functionality to the DECC 2050 Calculator.

Inorganic nanomaterials are widely used in diverse applications such as oil refining, food, coatings, cosmetics, textile, transport, healthcare and electronics and communication, with a global market worth 20 billion EURO. A recent inventory has documented >1800 consumer products that contain nanomaterials and many more non-commodity products such as industrial catalysts and separation media. However, there are limitations in terms of the sustainability of and the attainable product quality from current manufacturing. Industry uses wet (chemical precipitation) and dry (flame or plasma) processes for manufacturing nanomaterials. Despite the advances in the latter, it has been shown that the wet processes are lot more efficient than the dry processes. Anastas and co-workers performed a sustainability analysis for wet processes, which revealed that nanomaterials manufacturing is significantly wasteful when compared to the production of bulk chemicals. This creates an enormous burden on the environment and results in unsustainable manufacturing. Further, some of the key properties of nanomaterials cannot be obtained with existing manufacturing methods. Lab-based methods exist for synthesising nanomaterials of desired properties, however, these methods are very wasteful and uneconomical to scale-up. Hence such high value materials remain at small scales and commercially inaccessible. A World Technology Evaluation Center report, commissioned by the USA's National Science Foundation, explicitly recommended that achieving green manufacturing by 2020 is the "holy grail" and that future research should focus on emulating natural designs to develop scalable processes for manufacturing nanomaterials [Ref. Roco et al., Nanotechnology Research Directions for Societal Needs in 2020, NSF and WTEC, 2010]. I have developed fully synthetic novel bioinspired approaches to nanomaterials, with rapid reactions (takes only 1-5 minutes) at room temperature in water, producing almost no waste, yet providing superior control of product properties. This method can reduce the energy usage of the reaction step by ~95% when compared with a traditional precipitation process and the materials would as cheap as the lowest grade commercial counterparts, yet provide significantly better quality and properties. However, the bulk of research on bioinspired synthesis has been performed at small scales. The bioinspired method cannot be scaled-up yet because there is a critical gap in our knowledge on its scale dependence. This fellowship aims to apply bioinspired routes to deliver sustainable ("green"), low cost and scalable technologies for manufacturing high value functional nanomaterials. I will develop scale-up rules by modelling and experimentally measuring mixing mechanisms. I will design process chemistry to produce bespoke nanomaterials and demonstrate pathways for larger-scale manufacturing. This fellowship has a great potential to take the UK to the world leading stage in sustainable manufacturing of bespoke nanomaterials.

Industry is responsible for 25% of carbon dioxide emissions from the European Union with around 60% of these emissions coming from the energy-intensive chemical, petrol refining, cement, steel and cement industries. The products of these process plants are fundamental to the global economy however many of the corresponding manufacturing processes are operating at (or are close to) their maximum practical efficiency. This reduces the impact of any future efficiency improvement measures in reducing overall carbon dioxide emissions across the sector. Industrial Carbon Capture and Storage (ICCS) is considered by the International Energy Agency (IEA) as the "most important technology" to decarbonise the industrial sector. This technology couples into industrial process plants, separates out the carbon dioxide and transports it to a suitable location for long term underground storage. In this way, the process plants are no longer venting unwanted carbon dioxide emissions directly into the atmosphere. Whilst many of the key components in ICCS have been demonstrated in pilot scale projects, the deployment of a full scale system remains a challenge due to the high capital costs associated with developing the infrastructure for carbon dioxide capture, transportation and storage. One effective means to address these issues is to share the burden by developing regional clusters of industrial process plants which all feed into a common ICCS network. This project brings together a strong academic team from Newcastle University, Imperial College and Cambridge University with significant technical support from the International Energy Agency, industrial technical experts, various CCS clusters and demonstration sites. The project will be the first of its kind to evaluate multiple potential ICCS clusters planned worldwide and assess their impact on products and consumers. It will mainly focus on a cluster planned in Teesside, UK featuring a steel furnace, ammonia manufacturing site, a hydrogen reforming facility, and a chemical plant. It will collate technical data from many of the pilot demonstrations in the United States and Europe to gain a more comprehensive understanding of the required operation of other relevant energy intensive process plants such as petroleum refineries and cement production sites. This technical data will be used to develop a set of software design tools for the planning of ICCS clusters and develop a means to optimise their operation. In addition, a robust set of economic analysis tools will be developed to support evaluation of the economics and costs associated with the technology. The impact on the supply chain will be assessed through a comprehensive outreach and public engagement exercise. Ideas for new low-carbon products will be developed and their costs evaluated. This process will include surveys and focus groups to gain opinions and data from key stakeholders who operate in the supply chains of planned ICCS clusters. This will include regular communication with business-to-business customers right through to end-users and consumers. This will be used to gain a greater understanding of attitudes towards these potential lower-carbon products and to assess the strength of consumer pull under multiple carbon pricing/policy scenarios.