The aim is to exploit a recent discovery concerning the production of a new high activity catalyst for use in the production of organic carbonates. The methodology uses a new gold catalyst supported on an acidic support. Initial results show the new catalyst is over sixty times as active as the current equivalent commercial catalyst and retains complete specificity for the carbonate product. This enhanced activity represents a step change in the manufacturing processes for these important chemical building blocks. Funding is requested to complete patent exemplification and to ensure commercial exploitation can be achieved.

The aim is to exploit a recent discovery concerning the production of a new high activity catalysts based on supported metal nanoparticles prepared by a sol immobilization method. The methodology uses a novel method for removal of stabilizers thereby gaining enhanced activity. Initial results show the new catalyst is highly active for CO oxidation whereas the untreated catalyst is completely inactive. This enhanced activity represents a step change in the manufacturing processes for these important catalysts and means that they can be considered to be commercially useful for the first time. Funding is requested to complete patent exemplification and to ensure commercial exploitation can be achieved.

The report 'Higher Degree of Concern' by the Royal Society of Chemistry highlighted the importance of effective PhD training in providing the essential skills base for UK chemistry. This is particularly true for the many industries that are reliant on catalytic skills, where entry-point recruitment is already at PhD level. However, the new-starters are usually specialists in narrow aspects of catalysis, while industry is increasingly seeking qualified postgraduates equipped with more comprehensive knowledge and understanding across the cutting edge of the whole field. The 2011 EPSRC landscape documents acknowledged the existing strengths of UK catalysis (including the concentration of academic expertise in the south-west), but recognised the critical need for growth in this strategic and high-impact field of technology. Over the following 18 months, the universities of Bath, Bristol and Cardiff worked closely together to put in place the foundations of an alliance in catalysis, based on the distinctive but complementary areas of expertise within the three institutions. This bid will build on this alliance by creating a single training centre with unified learning through teaching and research. Building on the best practice of existing and established postgraduate training, and benefitting from the close geographical proximity of the three universities, each intake of PhD students will form part of a single cohort. The first year of the PhD will involve taught material (building on and expanding Cardiff's established MSc in catalysis), a student-led catalyst design project, and research placements in research laboratories across all aspects of catalysis science and engineering (and across all three institutions). This broad foundation will ensure students have a thorough grounding in catalysis in the widest sense, fulfilling the industry need for recruits who can be nimble and move across traditional discipline boundaries to meet business needs. It will also mean the students are well-informed and fully engaged in the design of a longer PhD project for the next three years. This project will be the same as the more traditional PhD in terms of its scholarship and rigour, but still include wider training aspects. A further benefit of the broader initial training is that students will be able to complete PhD projects which transcend the traditional homogeneous, heterogeneous, engineering boundaries, and include emerging areas such as photo-, electro- and bio-catalysis. This will lead to transformative research and will be encouraged by project co-supervision that cuts across the institutions and disciplines. We have identified a core of 28 supervisors across the three universities, all with established track records of excellence which, when combined, encompasses every facet of catalysis research. Furthermore, full engagement with industry has been agreed at every stage; in management, training, project design, placements and sponsorship. This will ensure technology transfer to industry when appropriate, as well as early-stage networking for students with their potential employers.

This proposal seeks funding to create a Centre for Doctoral Training (CDT) in Integrated Photonic and Electronic Systems. Photonics plays an increasing role in systems, ranging from sensing, biophotonics and manufacturing, through communications from the chip-to-chip to transcontinental scale, to the plethora of new screen and projection display technologies that have been developed, bringing higher resolution, lower power operation and enabling new ways of human-machine interaction. These advances have set the scene for a major change in commercialisation activity where photonics and electronics will converge in a wide range of information, sensing, communications, manufacturing and personal healthcare systems. Currently, systems are realised by combining separately developed photonic components, such as lasers and photodetectors with electronic circuits. This approach is labour intensive and requires many electrical interconnects as well as optical alignment on the micron scale. Devices are optimised separately and then brought together to meet systems specifications. Such an approach, although it has delivered remarkable results, not least the communications systems upon which the internet depends, limits the benefits that could come from the full integration of photonics with electronics and systems. To achieve such integration requires researchers who have not only deep understanding of their specialist area, but also an excellent understanding across the fields of electronic and photonic hardware and software. This proposal therefore seeks to meet this important need, building upon the uniqueness and extent of the UCL and Cambridge research, where research activities are already focussing on the direct monolithic integration of lasers with silicon electronics, new types of displays based on polymer and holographic projection technology, the application of photonic communications to computing, personal information systems and indeed consumer products (via board-to-board, chip to chip and later on-chip interconnects), the increased use of photonics in industrial processing and manufacture, techniques for the low-cost roll-out of optical fibre to replace the copper network, the substitution of many conventional lighting products with photonic light sources and extensive application of photonics in medical diagnostics and personalised medicine. Many of these activities will increasingly rely on more advanced electronic systems integration, and so the proposed CDT includes experts in electronic circuits, computer systems and software. By drawing these complementary activities together, and building upon initial work towards this goal carried out within our previously funded CDT in Photonic Systems Development, it is proposed to develop an advanced training programme to equip the next generation of very high calibre doctoral students with the required technical expertise, commercial and business skills, and thus provide innovation opportunities for the integration of photonic and electronics in new systems in the coming years. It should be stressed that the CDT will provide a wide range of methods for learning for research students, well beyond that conventionally available, so that they can gain the required skills. In addition to conventional lectures and seminars, for example, there will be bespoke experimental coursework activities, reading clubs, roadmapping activities, secondments to companies and other research laboratories and business planning courses. The integration of photonic and electronic systems is likely to widen the range of systems into which these technologies are deployed in other key sectors of the economy, such as printing, consumer electronics, computing, defence, energy, engineering, security and medicine. As a result, a key feature of the CDT will be a developed awareness in its student cohorts of the breadth of opportunity available and a confidence that they can make impact therein.