Light emitting semiconductor materials and devices dominate many aspects of everyday life. Their influence is all pervasive providing the sources which enable the internet, large area displays, room and street lighting to give just a few examples. Their existence relies on the high quality semiconductor structures which may be prepared by advanced crystal growth and sophisticated nanofabrication. Our proposal aims to capitalise on the advanced growth and fabrication to achieve similar advances in the quantum world where often counter-intuitive behaviour is governed solely by the laws of quantum mechanics. Our overall aim is to explore the behaviour of nano-devices operating in regimes where fundamentally new types of quantum-photonic phenomena occur, with potential to underpin the next generation of quantum technologies. We focus on two complementary systems: III-V semiconductors with their highly perfect crystal lattices, proven ability to emit photons one by one and long coherence quantum states, and atomically-thin graphene-like two dimensional (2D) semiconductors enabling new band structures, stable electron-hole bound states (excitons) and easy integration with patterned structures. The combination of the two material systems is powerful enabling phenomena ranging from the single photon level up to dense many-particle states where interactions dominate. A significant part of our programme focusses on on-chip geometries, enabling scale-up as likely required for applications. The semiconductor systems we employ interact strongly with photons; we will achieve interactions between photons which normally do not interact. We will gain entry into the regime of highly non-linear cavity quantum electrodynamics. Excitons (coupled electron-hole pairs) and photons interact strongly, enabling ladders of energy levels leading to on-chip production of few photon states. By coupling cavities together, we will aim for highly correlated states of photons. These advances are likely to be important components of photonic quantum processors and quantum communication systems. In similar structures, we access regimes of high density where electrons and holes condense into highly populated states (condensates). We aim to answer long-standing fundamental questions about the types of phase transitions that can occur in equilibrium systems and in out-of-equilibrium ones which have loss balanced by gain. We will also study condensate systems up to high temperatures, potentially in excess of 100K, and of the mechanisms underlying phase transitions to condensed states. The condensed state systems, besides their fundamental interest, also have potential as new forms of miniature coherent light sources. Nanofabrication will play a vital role enabling confinement of light on sub-wavelength length scales and fabrication of cavities for photons such that they have very long lifetimes before escaping. The ability to place high quality emitters within III-V nanophotonic structures will receive enhancement and potential world lead from a crystal growth machine we have recently commissioned, specially designed for this purpose, funded by the UK Quantum Technologies programme. Similar impact is expected from our ability to prepare 2D heterostructures (atomically thin layers of two separate materials placed one on top of the other) under conditions of ultrahigh vacuum free from contamination, enabling realisation of bound electron-hole pair states of very long lifetime, the route to condensation to high density states. The easy integration of 2D heterostructures with patterned photonic structures furthermore enables nonlinear and quantum phenomena to be studied, including in topological structures where light flow is immune to scattering by defects. Taken all together we have the ingredients in place to achieve ground-breaking advances in fundamental quantum photonics with considerable potential to underpin next generations of quantum technologies.

Thin films with a high technical specification are used in many everyday devices, including displays, solar cells, electronic devices, batteries, and sensors. Printing of the high-value flexible electronic films with insulating, dielectric, semiconducting and conducting materials used in these devices makes a major and rapidly growing contribution to UK industry.The thickness of the films required, the starting materials used and the final high-value functions desired in the finished product vary significantly. However, the scientific principles that govern the behaviour of the printing processes for these diverse applications have many similarities, because they are all formed by selectively spreading a wet film of suspended solid particles and drying it. At present the optimisation of the printing parameters for these films is commonly achieved through a trial and error process rather than systematic intelligent control. Individual processes are being optimised in isolation without cross-fertilization of knowledge. In a fast changing world, where disruption to supply chains or development of improved materials can change the process input materials, the need to reconfigure the formulations/printing parameters used increases. Furthermore, desired outputs can also change rapidly as the manufacturers and customers seek to meet changing demands of their market for example requiring more precise control of film parameters such as thickness and electrical properties. Adjusting to such continually moving goal posts by relying on trial and error testing is time-consuming, wasteful and costly. The responsive manufacturing technology we propose to develop will have sufficient flexibility to overcome such problems by utilizing intelligent machine learning to control the printing parameters in real-time and therefore maintain an optimized printing process robustly in the face of variations in feedstock materials and/or the required output. It is surprising that there has been no major attempt to implement this approach to process control and optimisation for solution printed materials. This is despite process monitoring and feedback-based optimisation being proven enabling methods in other sectors such as additive manufacturing. This will be achieved by developing control algorithms for the printing process that take into account our theoretical understanding of the processes occurring and utilizing high-speed (minimized and proxy) in situ data acquisition to respond autonomously and continuously to perturbations in the feedstock materials or required film properties. We will make use of the wide range of laboratory scale processing systems our project team regularly use for the production of model colloidal films, ceramic dielectrics, photovoltaics and battery electrodes to provide the datasets required to educate the machine learning algorithms, test our theoretical understanding, develop models of the printing processes and to ultimately test the autonomous control system that we develop. Having proven the system works at a laboratory scale we plan to perform a series of demonstration runs at industrial scale in collaboration with project partners CPI who are world leading experts in production of printed electronics. This will provide the evidence needed to prove that this approach can work at an industrial scale in a highly demanding production environment (printed electronics require a high degree of control of the surface chemistry between subsequent layers to perform correctly and are typically made in cleanroom/glove-boxes within strict environmental tolerances). We envisage a future where a deep theoretical understanding of the processes that are taking place is utilised by artificial intelligence to continuously control and optimise the manufacture of 21st century high-value printed films autonomously using the minimum number of high-speed measurements to achieve the desired results.

Solar photovoltaic (PV) technology is becoming a major source of renewable energy around the globe, with the International Energy Agency predicting it to be the largest contributor to renewables by 2024. This uptake is driven by the building of large PV power plants in regions of high solar resource, and also by the deployment of so-called distributed PV on the roofs of homes and industrial sites. The dominant PV technology to date has been based upon the crystalline semiconductor silicon. The production of silicon PV panels has been commoditised for large-scale manufacturing with costs reducing by a factor of ten in under a decade. Our research addresses the next generation of printed PV technologies which could deliver solar energy with far greater functional and processing flexibility than c-Si or traditional compound semiconductors, enabling tuneable design to meet the requirements of market applications inaccessible to current PV technologies. In particular, we seek to advance photovoltaics based upon organic and perovskite semiconductors - materials which can be processed from solution into the simplest possible solar cell structures, hence reducing cost and embodied energy from the manufacturing. These new technologies are still in the early stages of development with many fundamental scientific and engineering challenges still to be addressed. These challenges will be the foci of our research agenda, as will the development of solar cells for specific applications for which there is currently no optimal technological solution, but which need attributes such as light weight, flexible form factor, tuned spectral response or semi-transparency. These are unique selling points of organic and perovskite solar PV but fall outside the performance (and often cost) windows of the traditional technologies. Our specific target sectors are power for high value communications (for example battery integratable solar cells for unmanned aerial vehicles), and improved energy and resource efficiency power for the built environment (including solar windows and local for 'internet of things' devices). In essence we seek to extend the reach and application of PV beyond the provision of stationary energy. To deliver our ambitious research and technology development agenda we have assembled three world-renowned groups in next generation PV researchers at Swansea University, Imperial College London and Oxford University. All are field leaders and the assembled team spans the fundamental and applied science and engineering needed to answer both the outstanding fundamental questions and reduce the next generation PV technology to practise. Our research programme called Application Targeted Integrated Photovoltaics also involves industrial partners from across the PV supply chain - early manufacturers of the PV technology, component suppliers and large end users who understand the technical and cost requirements to deliver a viable product. The programme is primarily motivated by the clear need to reduce CO2 emissions across our economies and societies and our target sectors are of high priority and potential in this regard. It is also important for the UK to maintain an internationally competitive capability (and profile) in the area of next generation renewables. As part of our agenda we will be ensuring the training of scientists and engineers equipped with the necessary multi-disciplinary skills and closely connected to the emerging industry and its needs to ensure the UK stays pre-eminent in next generation photovoltaics.

This Centre for Doctoral Training (CDT) is in the field of Polymers, Soft Matter and Colloids. This area of science deals with long-chain molecules, gels, particles, pastes and complex fluids. It is of fundamental importance for many commercial sectors, including paints & coatings, home & personal care products, agrochemicals, engine oils & lubrication, enhanced oil recovery, biomedical devices & drug delivery. Thus substantial EPSRC investment in this industrially-relevant field will directly support the UK economy and enhance its competitiveness over the longer term, as well as contributing to our scientific capacity to address important technical challenges and major societal problems such as sustainability and energy security. Sheffield Polymer Centre academics have a wealth of research experience in the areas of polymer chemistry, polymer physics, colloid science, soft matter physics and polymer engineering. This breadth of expertise is unique and is certainly unrivalled anywhere in the UK. Between us, we offer a superb range of research facilities and state-of-the-art instrumentation that provide excellent postgraduate training opportunities. We have also run a popular annual industrial training course and three relevant taught MSc courses for many years. Thus the logistical experience of our current administrative staff and existing teaching infrastructure will provide invaluable support in running this new CDT. Moreover, this prior activity underlines our institution's deep commitment to this important interdisciplinary field. Our vision is to engage closely with a wide range of companies, e.g. AkzoNobel, Lubrizol, P & G, Cytec, Synthomer, Scott Bader, GEO, Wellstream, LBFoster, Philips, Ossila, Syngenta, DSM, Ashland, BP and Unilever, in order to provide the next generation of highly skilled PhD scientists with high-level technical skills, intellectual rigour, excellent communication skills, flexibility and business acumen. This is essential if we are to produce the creative problem-solvers that will be required to tackle the many formidable technical and societal challenges now facing mankind. Our ambition is to secure at least £2.0 million from our industrial partners in order to support fifty CASE PhD projects over five years. Six PhD studentships p.a. (i.e. thirty in total) are requested from EPSRC, which will be supplemented by a substantial institutional contribution of three studentships p.a. (i.e. fifteen in total). This institutional commitment is in recognition of the continuing strategic importance of this research area to the University of Sheffield. An additional studentship p.a. (i.e. five in total) will be funded by top-slicing the enhanced CASE contributions from our industrial partners to make up the annual cohort of ten students. EPSRC investment in this CDT is warranted given our substantial institutional portfolio of many active EPSRC grants (including Programme and Platform grants), plus a £2.0 M ERC grant. Our CDT training programme will include the following highly distinctive features: (i) our unrivalled breadth of academic knowledge and experience; (ii) a choice of research projects for our PhD students prior to their enrolment; (iii) an initial two-week training course on the basic principles of polymer science and engineering; (iv) a monthly seminar programme led by industrial scientists to expose our students to a wide range of commercially-relevant topics; (v) a six-month secondment with the industrial partner in the latter part of the research programme, which will provide our students with invaluable experience of the workplace and hence prepare them for their industrial and/or managerial careers; (vi) a 'business enterprise' course led by an external consultant (Jo Haigh) and one of our industrial partners (Synthomer) to develop and encourage entrepreneurial flair in each PhD cohort; (vii) a visit to an overseas academic laboratory to facilitate international collaboration.

We propose a Centre for Doctoral Training in New and Sustainable PV. It will support the transformation of PV in the UK will that will in turn aid the country to achieve its renewal energy obligations, and will generate jobs in the technology sectors as well as local manufacturing and installation. The CDT allows for the distributed nature of PV research in the UK with a multi-centre team of seven partners covering all aspects of PV research from novel materials through new device architectures to PV systems and performance. The PhD projects and training span engineering and physical science expertise in materials and device physics, electronic engineering, physical and synthetic chemistry, operations management and manufacturing. The CDT graduates will be capable of transforming state of the art R&D across the PV technologies and, in so doing, contribute to the production and implementation of improved PV products and systems. All partners are members of the SuperSolar Hub and hence already coordinate integrated PV research and training. Students in the CDT will join a thriving research community. The team has unrivalled access to shared facilities in the best state of the art laboratories in the UK. Our group approach brings together expertise with a breadth and depth for training and research that could not be assembled in any other way. Moreover, the collaboration allows us to cut across the traditional boundaries in PV and enables exciting research vectors to be followed in New and Sustainable PV CDT agenda. International collaborations and formal exchange agreements will emphasise the global aspects of advanced research that are important for the development of a leadership group. The CDT members will interact with related research themes such as photochemical conversion of fuels for energy and other applications, and heating and cooling by solar radiation and will be a proactive member of the UK wide Network of Energy CDTs. Our goal is to train the best researchers with a flexible mindset able to communicate across different disciplines and be leaders in the emerging PV industry for advanced technologies. We will provide the training required for graduates to join the sustainable energy and PV sectors. We will establish a real identity of purpose and commonality in each cohort through a training programme designed to give students an understanding of all aspects of PV, including implications for society and an experience of a commercial environment. Students will be provided with a bespoke curriculum and training programme that exposes them to: (i) underpinning fundamentals across all the relevant disciplines, (ii) current state-of-the-art in knowledge and challenges in scale-up and systems, and (iii) unparalleled opportunities to engage in leading-edge interdisciplinary research projects as part of a national team. We will create a doctoral training environment in which students benefit from leading academic expertise and world-class facilities to develop their knowledge as well as the tools to innovate and create within their selected research theme. The unique cross functional skill-sets that our graduates will have will make them highly valuable to the academic community seeking to address ambitious basic manufacturing research challenges, and to industry, who have an urgent need for appropriately trained scientists and engineers able to support PV technologies within their commercial operations. To allow the students the chance to develop a common sense of purpose, each cohort will attend training events together. Courses will cover fundamental aspects common to all PV technologies and also advanced courses based on the partners' research expertise. There will be industrial and international placements. Coherence across the CDT will be aided by a virtual collaboration medium containing webinars and video lectures and pages where students and staff can collaborate via groups, and online forums.