The nuclear industry has some of the most extreme environments in the world, with radiation levels and other hazards frequently restricting human access to facilities. Even when human entry is possible, the risks can be significant and very low levels of productivity. To date, robotic systems have had limited impact on the nuclear industry, but it is clear that they offer considerable opportunities for improved productivity and significantly reduced human risk. The nuclear industry has a vast array of highly complex and diverse challenges that span the entire industry: decommissioning and waste management, Plant Life Extension (PLEX), Nuclear New Build (NNB), small modular reactors (SMRs) and fusion. Whilst the challenges across the nuclear industry are varied, they share many similarities that relate to the extreme conditions that are present. Vitally these similarities also translate across into other environments, such as space, oil and gas and mining, all of which, for example, have challenges associated with radiation (high energy cosmic rays in space and the presence of naturally occurring radioactive materials (NORM) in mining and oil and gas). Major hazards associated with the nuclear industry include radiation; storage media (for example water, air, vacuum); lack of utilities (such as lighting, power or communications); restricted access; unstructured environments. These hazards mean that some challenges are currently intractable in the absence of solutions that will rely on future capabilities in Robotics and Artificial Intelligence (RAI). Reliable robotic systems are not just essential for future operations in the nuclear industry, but they also offer the potential to transform the industry globally. In decommissioning, robots will be required to characterise facilities (e.g. map dose rates, generate topographical maps and identify materials), inspect vessels and infrastructure, move, manipulate, cut, sort and segregate waste and assist operations staff. To support the life extension of existing nuclear power plants, robotic systems will be required to inspect and assess the integrity and condition of equipment and facilities and might even be used to implement urgent repairs in hard to reach areas of the plant. Similar systems will be required in NNB, fusion reactors and SMRs. Furthermore, it is essential that past mistakes in the design of nuclear facilities, which makes the deployment of robotic systems highly challenging, do not perpetuate into future builds. Even newly constructed facilities such as CERN, which now has many areas that are inaccessible to humans because of high radioactive dose rates, has been designed for human, rather than robotic intervention. Another major challenge that RAIN will grapple with is the use of digital technologies within the nuclear sector. Virtual and Augmented Reality, AI and machine learning have arrived but the nuclear sector is poorly positioned to understand and use these rapidly emerging technologies. RAIN will deliver the necessary step changes in fundamental robotics science and establish the pathways to impact that will enable the creation of a research and innovation ecosystem with the capability to lead the world in nuclear robotics. While our centre of gravity is around nuclear we have a keen focus on applications and exploitation in a much wider range of challenging environments.

One of the most pressing problems facing society today is the management of existing and future waste forms arising from nuclear energy production. Here, the redox chemistry of the actinide elements plays a crucial role in many aspects of nuclear fission including safe disposal strategies and new recovery and recycling routes. Understanding the chemistry of actinides in engineered environments is imperative for the management of existing and future fission products (nuclear waste) arising from nuclear power production, particularly for underground geological disposal. In particular, the redox chemistry of neptunium, a key radionuclide found in appreciable quantities in high level waste is complex, changeable and currently not well understood. Over the lifespan of the proposed geological disposal facility, one of the principal hazards is a change in chemistry of neptunium that may result in leaching from the repository, breaching primary containment and entering the engineered environment. Due to the particular complex redox and chemical speciation of neptunium, crucial mechanistic information on redox chemistry and speciation that affects its interactions with engineered and natural encapsulating materials including the host rock and backfill material is lacking and remains one of the principal chemical challenges facing this field. In this feasibility study, we will address the prospect of using one and two photon fluorescence and phosphorescence spectroscopy and microscopy as a non-destructive technique to address this problem. We aim to visualise, locate and spatially map the different oxidation states of neptunyl that can co-exist in solution in model conditions using well defined complexes and aqua ions in with the ubiquitous geologically relevant minerals silica, alumina and calcite at previously unseen levels of detail (sub micrometer resolution). We have recently demonstrated that neptunyl(V) and (VI) emission occurs in the green and blue regions of the electromagnetic spectrum and are equally as intense as the uranyl(VI) ion, whose optical properties are well known and have been used by us for fluorescence and phosphorescence microscopy imaging. This means that both oxidation states can be detected simultaneously so that highly sensitive, informative three-dimensional imaging can be used to understand neptunyl geochemistry below the micron scale. This will add much needed important information to the safety case for nuclear waste disposal in a range of heterogeneous systems.

The overarching goal of this project is to establish the technological potential, through a proof - of - concept study, of an entirely new family of glassy materials which could safely and stably incorporate high levels of CO2 by locking it away within the structure of the material in a stable form that is resistant to air, heat and light. In doing so it is believed this will present multiple new properties and in so doing this will enable transformative industrial changes in the way we manufacture, use, recycle and think about glass. There are three main pathways to academic and commercial impact: (1) UK glass industry and community (the primary route); (2) Multiple UK manufacturing sectors, specifically electronic devices and photonics; and (3) UK nuclear industry, specifically waste immobilisation and site license companies. Carboglass could provide multiple new innovation platforms for advanced materials and manufacturing technologies; carbon capture and storage; nuclear decommissioning; and energy and CO2 emissions reduction, thereby impacting upon policy, health and quality of life; delivering the capability to disrupt existing business models and contributing towards a more resilient, productive and prosperous nation. This research could lead to new technologies that provide the UK glass industry with CO2 emissions savings of up to 50% (1.25MT/yr) and increase resource efficiency by up to 20% (1 MT/yr, saving £100M/yr). It could also provide a new path for treatment of carbon-rich radioactive wastes, and could become a leading carbon capture and storage (CCS) technology. This disruptive development could lead to new high-skilled UK jobs and offer a technology platform for uptake by other industries. The proposed research will take the form of 3 work packages (WP's) that will lead to proof-of-concept, as follows: WP1. CO2 incorporation (Months 1-20). Determine key chemical, structural and processing factors governing CO2 incorporation in materials. Materials incorporating CO2 will be produced. Outcomes: relations mapped in model systems, boundaries defined. WP2. Composition / structure / property relations (Months 3-24). Map relations in model materials with focus on CO2 incorporation and physical / chemical properties. Outcomes: fundamental understanding of effects of CO2 incorporation on material properties and structure achieved. WP3. Carboglass technology development (Months 12-24). Build / disseminate understanding of research needs to enable development of Carboglass technology towards high volume manufacturing. Outcomes: clear understanding of research needs for development of Carboglass technology, with initial upscaling designs disseminated widely to academic and industrial partners. Public benefits of this research will include improved environment and quality of life (lower CO2 emissions and energy use; safer nuclear waste, new functional materials leading to new products and processes); disruption of business models (UK jobs and wealth creation); and raised public interest in science and technology. Carboglass represents an opportunity for the UK to lead the world in new, clean and green technologies and simultaneously provides multiple new pathways for a resilient, productive and healthy UK.

The vision for this Programme is to deliver the step changes in Robotics and Autonomous Systems (RAS) capability that are necessary to overcome crucial challenges facing the nuclear industry in the coming decades. The RAS challenges faced in the nuclear industry are extremely demanding and complex. Many nuclear installations, particularly the legacy facilities, present highly unstructured and uncertain environments. Additionally, these "high consequence" environments may contain radiological, chemical, thermal and other hazards. To minimise risks of contamination and radiological shine paths, many nuclear facilities have very small access ports (150 mm - 250 mm diameter), which prevent large robotic systems being deployed. Smaller robots have inherent limitations with power, sensing, communications and processing power, which remain unsolved. Thick concrete walls mean that communication bandwidths may be severely limited, necessitating increased levels of autonomy. Grasping and manipulation challenges, and the associated computer vision and perception challenges are profound; a huge variety of legacy waste materials must be sorted, segregated, and often also disrupted (cut or sheared). Some materials, such as plastic sheeting, contaminated suits/gloves/respirators, ropes, chains can be deformed and often present as chaotic self-occluding piles. Even known rigid objects (e.g. fuel rod casings) may present as partially visible or fragmented. Trivial tasks are complicated by the fact that the material properties of the waste, the dose rates and the layout of the facility within which the waste is stored may all be uncertain. It is therefore vital that any robotic solution be capable of robustly responding to uncertainties. The problems are compounded further by contamination risks, which typically mean that once deployed, human interaction with the robot will be limited at best, autonomy and fault tolerance are therefore important. The need for RAS in the nuclear industry is spread across the entire fuel cycle: reactor operations; new build reactors; decommissioning and waste storage and this Programme will address generic problems across all these areas. It is anticipated that the research will have a significant impact on many other areas of robotics: space, sub-sea, mining, bomb-disposal and health care, for example and cross sector initiatives will be pursued to ensure that there is a two-way transfer of knowledge and technology between these sectors, which have many challenges in common with the nuclear industry. The work will build on the robotics and nuclear engineering expertise available within the three academic organisations, who are each involved in cutting-edge, internationally leading research in relevant areas. This expertise will be complemented by the industrial and technology transfer experience and expertise of the National Nuclear Laboratory who have a proven track record of successfully delivering innovation in to the nuclear industry. The partners in the Programme will work jointly to develop new RAS related technologies (hardware and software), with delivery of nuclear focused demonstrators that will illustrate the successful outcomes of the Programme. Thus we will provide the nuclear supply chain and end-users with the confidence to apply RAS in the nuclear sector. To develop RAS technology that is suitable for the nuclear industry, it is essential that the partners work closely with the nuclear supply chain. To achieve this, the Programme will be based in west Cumbria, the centre of much of the UK's nuclear industry. Working with researchers at the home campuses of the academic institutions, the Programme will create a clear pipeline that propels early stage research from TRL 1 through to industrially relevant technology at TRL 3/4. Utilising the established mechanisms already available in west Cumbria, this technology can then be taken through to TRL 9 and commercial deployment.