The drive towards more sustainable technologies relies on developing improved catalytic materials; greater activity and selectivity to desired products with ever decreasing amounts of expensive catalyst metals. Supported metal nanoparticles are a cornerstone within the field of heterogeneous catalysis; the metal support interaction aids the stability of the catalyst and promotes chemical reactions. Controlling the interface of composite structures is a key part of this synergy between metal nanoparticle and metal oxide support. Supported metal nanoparticles are most commonly prepared by the impregnation of metal oxide hosts, followed by a thermal activation. The concept of the project is to use metal nanoparticles supported on MOFs as templates. The intention is to remove the organic linkers through chemical means, i.e. by introducing strong reductants such as NaBH4, producing tailored nanocomposites. Indeed, we have recently performed a proof-of-concept study where we were able to prepare PdCu/Cu2O nanocomposites from Pd/Cu-BTC templates. The programme of work will: (i) Show how systematic variations to preparation conditions influences the composite structure. (ii) Demonstrate their importance for emerging catalytic applications in sustainable energy generation (i.e formic acid decomposition). (iii) Use advanced characterisation under process conditions to understand the formation of the composite structure and how the structures evolve during catalysis.

It is not possible to understand the way that a fuel cell operates without understanding how reactants, products, heat and electrochemical potential varies within that fuel cell. A consequence of this is that in order to obtain the best performance out of a fuel cell we cannot treat it like a simple electrical device with a positive and negative terminal: we need to be able to understand what is happening at different points within that fuel cell. Put simply, the purpose of this project is to develop a new way to image what is happening within an operating fuel cell. That is, to develop a way in which we can see how well the different parts of the fuel cell is operating - whether they are operating well, or starved of reactants, or undergoing damaging processes which will limit the longevity of the system.In this programme we intend to build on previous work at NPL, Imperial and UCL to develop a world-class instrument to allow us to study what is happening within an operating fuel cell. We will utilise a specially instrumented fuel cell which will allow us to monitor several very important parameters in real time. In this way we can monitor how the fuel cell operates under the different extreme conditions imposed on it during both normal and abnormal operating conditions. Examples of such extreme conditions occur when the fuel cell is started up, or shut down or when the fuel cell is pushed to perform at the limits of its performance (as might be expected during an overtaking manoeuvre if the fuel cell were powering a vehicle). Results of this research will be utilised to improve the design of the fuel cell.The hardware will be designed and built at Imperial College, and tested at both Imperial and NPL. A bipolar plate rapid prototyping facility will be built at UCL which will allow us to experiment with different flow-field geometries in order to achieve as even as possible distribution of the parameters being measured with the fuel cell mapping hardware. Modelling will be performed at UCL in order to test improvements to the performance of the cells brought about by using different flow-field architecturesWe have engaged with two major UK fuel cell companies, Johnson Matthey and Intelligent Energy, who are interested in utilising the instrumentation and results of this work.

The development of the Haber Bosch Process for the synthesis of ammonia on an industrial scale was one of the major achievements of the 20th Century. It can be directly credited with sustaining the global population through the provision of an accessible route to synthetic fertilizers. The process is based upon the reaction of pure N2 and H2 feedstreams over a promoted iron based catalyst. It is operated at high pressure (>100 atmospheres) and moderate temperature and the process as a whole currently accounts for a significant proportion of global energy demand (>1%). In this research, we are attempting to develop alternative catalysts which will contribute to energy savings by facilitating the reaction at lower reaction temperatures (where there is a thermodynamic advantage.) The approach to be taken will involve a mixture of computational design and experimental testing and is based upon previous studies of metal nitride catalysts which exhibit interesting activity for ammonia synthesis. Metal nitrides potentially contain "activated" nitrogen within their structure and it is the reactivity of this lattice nitrogen which which could be the key to their high activity. Using computational modelling, understanding of experimental results will be obtained and will be extended to the identification of nitride materials of potential high catalytic activity. In parallel laboratory experiments, the identified materials will be synthesised and tested and the results fed back into the computational modelling to provide improved understanding. In this way, optimal catalyst formulations will be identified and these will be prepared and tested under industrially relevant ammonia synthesis conditions and the results will be compared to those from conventional industrially applied iron based catalysts.

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

The internal combustion engine which is in everyday use in a wide variety of applications remains one of the most cost effective means of generating power. A typical engine however loses substantial amounts of energy in its normal operation and there is clear potential to utilise this energy. The largest flow is in the exhaust system of the vehicle, and it is here that the proposed research is focussed. The main objective of the project is the realisation of an efficient method of energy recovery using a thermoelectric generator and utilising a new type of material known as a skutterudite. By adopting the same internal structure, skutterudites simulate a naturally occurring mineral which has the vital properties of low thermal conductivity with low electrical resistance. The principal advantage of these materials is their potential for cost reduction by utilising low cost metals in their structure. A second and important advantage is the future potential for novel manufacturing techniques in which the active elements of the thermoelectric generator are made using additive methods to build up the kind of complex shapes that are required. The project brings together three universities that can cover the range of capabilities from the chemistry of materials through to systems integration methods. The Heriot-Watt team will synthesise new materials using progressively lower cost materials to demonstrate that the required thermoelectric performance can be obtained using low cost materials. The Cardiff team will integrate modules, incorporating protective coatings to ensure the durability of the generator. At Loughborough, the scope to integrate thermo-electric (TE) generators with other functions such as after-treatment will be explored. The Loughborough team will work with the Cardiff team to identify novel methods of integrating the TE modules into a heat exchange device, regarding the requirements imposed by different types of engine. The project concludes with the practical demonstration of TE generators and a portfolio of simulation results that demonstrate how the cost path and the path to levels of commercial performance will be realised.